Can I modify, or create new, buttons in the quick access toolbar

J

Jose-EMV

I would like to create a modified version of the "print" button to the Quick
Access Toolbar in MS Word 2007 - where the modified button will trigger an
macro that I set up to print to a different tray in my printer.
What is the default location of these graphic files for the buttons, and can
I use Photoshop, for example, to create a modified version?
 
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