No, you can't turn a Number field into an AutoNumber field.
Select the table in the Database window.
Copy (Ctrl+C), and Paste (Ctrl+V).
Answer the dialog that you want the structure only, and supply a new name.
Open in design view. Delete the Number column. Save.
Add an AutoNumber column. Save.
Create a query into the old table.
Change it to an Append query (Append on Query menu), and tell it you want to
append to the new table.
Run the query. This imports all the old records into the new.
You now have a new table, with an AutoNumber column, and the data with the
values you wanted. You can delete your old table.